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Both sodium hydroxide and calcium hydroxide are inorganic bases. Calcium hydroxide is traditionally called slaked lime, and sodium hydroxide is often called lye or caustic soda. Calcium hydroxide is a colorless crystal or white powder. Sodium hydroxide is available in semi-clear pellets or blanks or in a stock solution. Both have industrial and household applications.
Chemistry
Sodium hydroxide and calcium hydroxide have important differences 4. Sodium hydroxide has one hydroxyl group and calcium hydroxide has two hydroxyl groups. The Centers for Disease Control explains that when you mix sodium hydroxide with water or acid, the reaction is so exothermic that nearby combustible materials may ignite 3. Although calcium carbonate is equally reactive, a comparison of Material Safety Data Sheets for both chemicals shows that it is less hazardous.
Sources
What Is Sodium Metasilicate?
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Calcium hydroxide can be prepared by treating calcium oxide with water. Alternatively, it can be synthesized by mixing solutions of calcium chloride and sodium hydroxide.
Sodium hydroxide is industrially prepared using the chloralkali process, which involves the electrolysis of a sodium chloride solution. Chlorine and hydrogen are other products of this reaction.
- Calcium hydroxide can be prepared by treating calcium oxide with water.
- Alternatively, it can be synthesized by mixing solutions of calcium chloride and sodium hydroxide.
Uses
Calcium hydroxide is used as a flocculant. Flocculants clarify solutions by removing small particles. It is also used to produce kraft paper. It is a common ingredient in building materials such as mortar, plaster and whitewash and in personal care depilatories.
Sodium hydroxide is found in oven and drain cleaners 2. Industrially, it is used in soap making, aluminium etching and cocoa processing. It is a common lab reagent.
- Calcium hydroxide is used as a flocculant.
- Industrially, it is used in soap making, aluminium etching and cocoa processing.
Safety
Chlorine & Bromine Allergy
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While calcium hydroxide and sodium hydroxide are both corrosive, calcium hydroxide is less so. Both burn the skin and airways upon contact. Both are potentially lethal poisons. Get prompt medical care if you ingest either of these chemicals. Do not induce vomiting, because that will only expose more tissue to the chemical. Treat skin burns by flushing with water.
- While calcium hydroxide and sodium hydroxide are both corrosive, calcium hydroxide is less so.
- Both burn the skin and airways upon contact.
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References
- EPA; Inorganic Chemical Industry 8.11 Chlor-Alkali; 1995
- Medline Plus: Sodium Hydroxide Poisoning
- Centers for Disease Control -- Toxic Substances Portal; Sodium Hydroxide
- Medline Plus: Calcium Hydroxide Poisoning
- Infirst Healthcare, Inc. Mylanta Maximum Strength Liquid Antacid/Anti-Gas.
- Infirst Healthcare, Inc. Mylanta Tonight Liquid Antacid/Anti-Gas.
- Infirst Healthcare, Inc. Mylanta Gas Minis.
- MedlinePlus, National Institutes of Health U.S. National Library of Medicine. Aluminum Hydroxide and Magnesium Hydroxide. Revised May 15, 2019.
- MedlinePlus, National Institutes of Health U.S. National Library of Medicine. Calcium Carbonate. Revised September 15, 2015.
- MedlinePlus, National Institutes of Health U.S. National Library of Medicine. Simethicone. Revised February 15, 2018.
Writer Bio
Shelly Morgan has been writing and editing for over 25 years for various medical and scientific publications. Although she began her professional career in pharmacological research, Morgan turned to patent law where she specialized in prosecuting patents for medical devices. She also writes about renal disease and hypertension for several nonprofits aimed at educating and supporting kidney patients.